The suitable substrates for hydrogen production have been assigned with respect to different production method. Anaerobic fermentative microorganism, cyanobacteria and algae are suitable in biological production of hydrogen via hydrogenase due to reversible. In the process, some electrons are directly transfered to the proton to generate hydrogen gas. Biological hydrogen production university of birmingham. Biohydrogen production through dark fermentation using organic waste as a substrate has gained increasing attention in recent years, mostly because of the economic advantages of coupling renewable, clean energy production with biological waste treatment. Biohydrogen production from waste materials article pdf available in enzyme and microbial technology 385. Biofuels are anticipated to enable a shift from fossil fuels for renewable transportation and manufacturing fuels, with biohydrogen considered attractive since it could offer the largest reduction of global carbon budgets. Among these substrates, many industrial wastewaters such as pharmaceutical, textile and food processing industry wastewaters have showed inhibition to the hydrogen production, due to the presence of toxic compounds such as phenols. In the introduction, properties of different fuels and yields of. Biohydrogen production as a potential energy resource. Hydrogenases are present in all three domains of life, archaea methanogens and some extremophiles, the bacteria the rest of the procaryotes and the eucaryotes in particular the green algae. Enhanced biohydrogen production by accelerating the. In mexico, the industrial production of tequila leads to the discharge of more than 31. Strategies to improve process efficiency through microbial routes.
Currently, lignocellulosic biohydrogen production remains inefficient with pretreatments that are heavily fossil fueldependent. Biohydrogen production through dark fermentation sarangi. Published data on biohydrogen also suggested that biohydrogen production from the asian countries is mainly focusing on dark fermentation, whilst the european countries are focusing on dark and photofermentation. Green algae, under anaerobic conditions, can either use h 2 as an electron donor in the co 2fixation process or evolve h 2. Xiao and liu reported sewage sludge sterilization at. Biohydrogen the microbiological production of hydrogen. Carbon savings for biohydrogen are more than four times greater than alternative technologies. A requisite byproduct of nitrogen fixation includes the production of hydrogen gas h2, which can be used for many applications, including renewable hydrogen fuel cells. In conclusion, some significant advances were made during this project, although an indirect biophotolysis process using cyanobacteria and using the photobioreactors was not demonstrated. Hydrogen is a renewable, clean source of energy which has a great potential to be an alternative fuel. The latest news and information on development of hydrogen technology in europe is available from the fuel cells and hydrogen joint undertaking fch ju a unique public private partnership supporting research, technological development and demonstration rtd activities in fuel cell and hydrogen energy technologies in europe. Among the various renewable energy sources, biohydrogen is gaining a lot of traction as it has very high efficiency of conversion to usable power with less pollutant generation.
Based on the mode of h2 generation, the biological routes for h2 production are categorized into four. Sago biomass as a sustainable source for biohydrogen production by clostridium butyricum a1 mohd azwan jenol, a mohamad faizal ibrahim, a phang lai yee, a madihah md salleh, b and suraini abdaziz a, biohydrogen production from biomass is attracting many researchers in developing a renewable, clean and environmental friendly biofuel. Conclusion 35 bio hydrogen is fuel of future areas of research to increase efficiency include developing of oxygen tolerant hydrogenase and increased hydrogen production rates. Bioprocessing and bioproduct engineering laboratory. A streamlined strategy for biohydrogen production with. An ideal approach is the use of selected microbial inocula that are able to degrade complex organic substrates with simultaneous. Biohydrogen production and kinetic modeling using sediment. Biohydrogen production from organic wastes jianlong wang. Therefore demand on hydrogen production has increased considerably in recent years. One platform is based on the microbial fermentation of sugars i. The pretreatment of inoculum were helpful in suppressing the. This book provides indepth information on basic and applied aspects of biohydrogen production. Biohydrogen, or hydrogen produced from renewable resources such as water or organic wastes by biological means, is a goal worthy of increased global attention and resources.
The various technologies available for the production of biohydrogen from lignocellulosic biomass such as direct biophotolysis, indirect biophotolysis, photo, and dark fermentations have some drawbacks e. Biohydrogen production from sugar rich substrates using the dark fermentation process phd thesis, the thesis will be available as a pdf file for downloading from the homepage of the department. Although biohydrogen production by darkfermentation is promising and advantageous over photofermentation 27. The bioreactors containing uv photolysis and tio2 adsorption pretreated wass and the control reactor require 0. In the introduction, properties of different fuels and yields of hydrogen are discussed.
Microbial conversion of waste biomass is the most successful technology for the generation of biohydrogen through dark fermentation. Hydrogen is a valuable gas as a clean energy source and as feed stock for some industries. Another method, called partial oxidation, produces. Incidentally, thermochemically produced h 2 is also being termed as biohydrogen due to the usage of biomass as a substratefeedstock. Biohydrogen production from sterilized sewage sludge as a. Biohydrogen production from sugar rich substrates using. The pdf file you selected should load here if your web browser has a pdf reader plugin installed for example, a recent version of adobe acrobat reader if you would like more information about how to print, save, and work with pdfs, highwire press provides a helpful frequently asked questions about pdfs alternatively, you can download the pdf file directly to your computer, from where it. The major advantage of energy from biohydrogen is the avoidance of greenhouse gas emissions. However, the reliance on fossil fuels leads to the significant. Generation of h 2 gas either by biological machinery or through thermochemical treatment of biomass can be defined as biohydrogen. An anaerobic continuous stirred tank reactor with working volume of. Published articles on biohydrogen research are highest from china followed by the usa and india.
Yubin zheng, jingwei ma, zhanyou chi, and shulin chen. Hydrogen production potential hpp from various feedstocks has been demonstrated wang et al. A most attractive route for developing biohydrogen technology is through a plant focussed on biosng production with some demonstration of hydrogen production. A comparable biohydrogen production was also obtained by c. Biodiesel and biohydrogen coproduction with treatment of high solid food waste. Enhancement of biohydrogen production via ph variation using. The dark fermentative hydrogen production is improved by pretreating the substrate or inoculum. The aim of this research was to study the feasibility of a fixed bed reactor for the production of biohydrogen by using tequila vinasse as substrate. However, the requirement of organic biomass as a feedstock makes this process quite expensive 28.
Biohydrogen production from palm oil mill effluent by. Overview of biohydrogen production technologies and. It begins with an introduction to the topic, and follows with the basic scientific. Clarian t who all provided valuable advice on the production of biohydrogen. Nrel is developing biological hydrogen h 2 production technologies from sustainable resources to help answer the nations need for renewable energy we have developed two renewable platforms for sustainable hydrogen production. Biohydrogen and bioethanol production from biodieselbased. Firstly is an anaerobic hydrogen fermenting bacterium are capable to use sugars and carbohydrates riches, readily available and wide variety waste and biomass. Hydrogen promises to be the most significant fuel source of the future, due to its global availability and the fact that water is its only byproduct. Biohydrogen is a natural and transitory byproduct of various microbialdriven biochemical reactions. Interest is high in this technology because h 2 is a clean fuel and can be readily produced from certain kinds of biomass many challenges characterize this technology, including those intrinsic to h 2, such as storage and transportation of a noncondensible gas. Pdf biohydrogen production integrated with an external. Biohydrogen production an overview sciencedirect topics. Pdf this paper provides an overview of the recent advances and trends in research in the biological production of hydrogen biohydrogen.
Biohydrogen production by dark fermentation is found most promising as compared to other biohydrogen production processes like photo fermentation process using photofermentative bacteria, microalgae, microbial fuel cell etc. Tio2 photocatalytic pretreatment accelerated the biohydrogen production from 10fold diluted was. The cost per tonne of carbon dioxide saved is 75% lower than smr hydrogen. Optimization of ammonium and biohydrogen production from. Biohydrogen production from tequila vinasses using a fixed. Three biohydrogen production technologies have been discussed above and dark fermentation process seems to be an attractive route for renewable production of hydrogen for a many reasons. Potential biomass that could be the substrates for biohydrogen generation include food and starchbased wastes, cellulosic. The thesis will be available as a pdffile for downloading from the homepage of. Ashok pandey, joshu chang, patrick c hallenbeck and christian larroche. Biohydrogen production by anaerobic fermentation is well known to be the most suitable, due to its potential for direct utilization of wastewater and organic waste ganguly et al. Strategies to improve process efficiency through microbial routes article pdf available in international journal of molecular sciences 164.
Mixed microbial consortia of enterobacter cloaceae and clostridium pasteurinum were used for the biohydrogen production. Show full abstract biohydrogen production and describes the prospects of combining biohydrogen production systems with fuel cell technology. The purpose of biohydrogen 97 was to bring together leaders in the biological p duction of hydrogen from the united states, japan, europe, and elsewhere to exchange. A road map on biohydrogen production from organic wastes. Photosynthetic production of hydrogen from water is a biological process that can convert sunlight into useful, stored chemical energy by the following general reaction. Abundant biomass from various industries could be a source for biohydrogen production where combination of waste treatment and energy production would be an advantage. Biohydrogen production from industrial wastewaters water. Disclaimer this document is issued for the party which commissioned it and for specific purposes connected with the abovecaptioned project only. Figure 1 combined hydrogen production potential from biomass, wind and solar top and current hydrogen production from natural gas using steammethane reforming smr and potential hydrogen production from coal bottom. For future engine fuel demands covers the production, purification, storage, pipeline transport, usage, and safety of biohydrogen. Biohydrogen production is considered a development vital to a sustainable global clean energy supply and a promising alternative to conventional fossil fuels, as it has the potential to eliminate most of the problems that fossil fuels create, if not all.
Pdf biohydrogen production and bioprocess enhancement. Biohydrogen production from microalgae 211 to protect the rights of the authors and publisher we inform you that this pdf is an uncorrected proof for internal business use only. Biohydrogen production download ebook pdf, epub, tuebl, mobi. Sago biomass as a sustainable source for biohydrogen. Effect of inlet velocity on heat transfer process in a. With a high substrate conversion efficiency 90%, a twostage approach, i. The maximum hydrogen production rate hpr and the cumulative hydrogen production chp were 0. Biological hydrogen production at the university of birmingham. Biodiesel and biohydrogen coproduction with treatment of. A series of batch fermentation were performed at 37c by feeding the anaerobic sludge bacteria with molasses to determine the effect of initial ph in the range of. Biohydrogen production from enzymatic hydrolysis of food. A detailed study has been conducted regarding the methods of production, the types of reactors and rawmaterials required. A variety of processes are potentially available, among them microbiological hydrogen production biohydrogen. In this study, the feasibility of biohydrogen production from enzymatic hydrolysis of food waste was investigated.
Hydrogen is seen by many as the fuel of the future because it has a very high energy density, three times that of petrol or diesel, and because its use produces only water instead of greenhouse gases and other exhaust pollutants. Results showed that due to scaleup effects, the lag phase increased from 0. The demand for improvement of the hydrogen production by dark hydrogen. One potential alternative is biohydrogen h2, a clean energy carrier with high energy yields. The current fossil fuelbased generation of energy has led to largescale industrial development. Recent hydrogenproduction techniques are classified. Hydrogen production by these bacteria is highly dependent on the process conditionss such as. Biohydrogen production from lignocellulosic biomass. Biohydrogen production is based on h2 producing enzymes, the hydrogenases and nitrogenases. This process, called steam methane reforming, accounts for about 95% of the hydrogen used today in the u. Outdoor h2 production in a 50l tubular photobioreactor by means of a sulfurdeprived. Hydrogen production by these bacteria is highly dependent on.
The judgements drawn in the report are offered as informed opinion. It begins with an introduction to the topic, and follows with the basic scientific aspects of biohydrogen production, such as the. Biohydrogen the microbiological production of hydrogen fuel. Hydrogen gas is a high energy 122 kjg clean fuel which can. Figure 1 a compares the biohydrogen production obtained in the 3.502 961 223 530 1422 1376 1238 143 809 1441 186 409 1315 1112 827 1206 670 1320 3 346 486 225 1248 1008 513 732 1018 1500 630 89 1087 1331 1280 1412 1385 341 494 528 467